کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7713737 | 1497427 | 2015 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The synthesis of PdPt/carbon paper via surface limited redox replacement reactions for oxygen reduction reaction
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
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چکیده انگلیسی
Surface-limited redox replacement reactions using the electrochemical atomic layer deposition (EC-ALD) technique were used to synthesize PdPt bimetallic electrocatalysts on carbon paper substrate. Electrocatalysts having different Pd:Pt ratio were electrodeposited by varying the deposition cycles of Pd and Pt. Diverse structural shapes of PdPt electrocatalysts were obtained with scanning electron microscopy (SEM). Higher number of deposition cycle produced more agglomerates and less dense particles on the support surface. The EDX profiles confirmed the presence of Pd and Pt particles on carbon paper. Cyclic voltammograms (CV) and linear scanning voltammetry (LSV) in oxygen showed that the electrodeposited catalysts were active for ORR and some were less affected by the methanol introduced in the vessel.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 40, Issue 46, 14 December 2015, Pages 16734-16744
Journal: International Journal of Hydrogen Energy - Volume 40, Issue 46, 14 December 2015, Pages 16734-16744
نویسندگان
Rapelang G. Motsoeneng, Remegia M. Modibedi, Mkhulu K. Mathe, Lindiwe E. Khotseng, Kenneth I. Ozoemena,