کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7715328 | 1497443 | 2015 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Phase stability and electric conductivity of Eu2O3-Tb4O7 co-doped Bi2O3 electrolyte
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Phase stability and electric conductivity of Eu2O3-Tb4O7 co-doped Bi2O3 electrolyte Phase stability and electric conductivity of Eu2O3-Tb4O7 co-doped Bi2O3 electrolyte](/preview/png/7715328.png)
چکیده انگلیسی
In this study, eight different samples of Tb4O7 and Eu2O3 co-doped Bi2O3 were prepared by solid-state synthesis techniques. (Bi2O3)1âxây(Tb4O7)x(Eu2O3)y (x = 5,10; y = 5, 10, 15, 20 mol%) ternary systems were investigated by using X-ray powder diffraction (XRD), differential thermal analysis/thermal gravimetry (DTA/TG), and four-point probe techniques (4PPT). Effect of concentration of doping elements on the temperature and electrical conductivity was investigated. All samples were evaluated by calculating activation energies and average crystal sizes. XRD measurements show that five samples have a single phase (δ-phase) structure. According to electrical conductivity measurements, the conductivity increases with increasing temperature but decreases with increasing amount of Eu2O3. The highest ionic conductivity was measured as 7.28 Ã 10â1 (ohm.cm)â1 for the (Bi2O3)0.90(Tb4O7)0.05 (Eu2O3)0.05 sample at 850 °C and the lowest activation energy was measured as 0.64 eV for (Bi2O3)0.90(Tb4O7)0.05 (Eu2O3)0.05.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 40, Issue 30, 10 August 2015, Pages 9485-9490
Journal: International Journal of Hydrogen Energy - Volume 40, Issue 30, 10 August 2015, Pages 9485-9490
نویسندگان
Ä°smail ErmiÅ, Mehmet Arı, Semra DurmuÅ Acer, Yılmaz DaÄdemir,