کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7715968 | 1497462 | 2015 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
On the manufacture of silver-BaCe0.5Zr0.3Y0.16Zn0.04O3âδ composites for hydrogen separation membranes
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Silver- BaCe0.5Zr0.3Y0.16Zn0.04O3âδ (Ag/BCZYZ) composites were investigated due to their potential application as hydrogen separation membranes, with emphasis on their fabrication and characterization. A precursor powder of BCZYZ was prepared via a wet chemical route and characterized by XRD, SEM and dilatometry. The precursor powder was coated with silver using Tollens reaction and then sintered under a variety of conditions. It was possible to obtain dense samples with a low level of non-percolating silver (2 vol%). Silver was present even if sintered at 1300 °C as it remained trapped in the ceramic matrix. The overall conductivity of a dense sample with 2 vol% of silver increased when compared to pure BCZYZ, and in particular the grain boundary resistance decreased considerably. A measurement of the open circuit voltage in fuel cell mode indicates the presence of mixed electronic-protonic conductivity in the composite.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 40, Issue 11, 22 March 2015, Pages 4146-4153
Journal: International Journal of Hydrogen Energy - Volume 40, Issue 11, 22 March 2015, Pages 4146-4153
نویسندگان
Enrique Ruiz-Trejo, Yuning Zhou, Nigel P. Brandon,