کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7716336 | 1497468 | 2015 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis of poly (2-Methoxyaniline)/sodium dodecyl sulfate film including bimetallic Pt-Cu nanoparticles and its application for formic acid oxidation
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
In this work, a facile, low cost and environmental friendly method without the use of any linking chemicals, i.e. galvanic replacement (transmetalation) is used for preparation of bimetallic Pt-Cu nanoparticles (NPs) onto highly porous poly (2-Methoxyaniline)/sodium dodecyl sulfate (P2MA-SDS) film. Electrochemical response of the prepared P2MA at the presence of SDS in 0.5Â M H2SO4 solution is, at least, 18 times higher than that obtained in the absence of SDS at the carbon paste electrode surface. The prepared bimetallic Pt-Cu NPs are verified by scanning electron microscopy (SEM), energy dispersive spectroscopy and electrochemical methods. The SEM images reveal that SDS strongly influences morphology of the polymer film. The Pt-Cu NPs formed on the P2MA-SDS film are with average sizes about 65Â nm. The obtained results from cyclic voltammetry and chronoamperometry reveal that the Pt-Cu NPs demonstrate enhanced electrocatalytic activity towards formic acid oxidation. Furthermore, the effects of several parameters such as P2MA thickness, 2Â MA, and SDS concentrations towards formic acid oxidation as well as long-term stability of the electrocatalyst have been investigated.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 40, Issue 5, 9 February 2015, Pages 2182-2192
Journal: International Journal of Hydrogen Energy - Volume 40, Issue 5, 9 February 2015, Pages 2182-2192
نویسندگان
Sayed Reza Hosseini, Rahman Hosseinzadeh, Shahram Ghasemi, Nahid Farzaneh,