کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7716493 | 1497468 | 2015 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
1,2-Dimethylimidazolium-functionalized cross-linked alkaline anion exchange membranes for alkaline direct methanol fuel cells
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The cross-linked and alkali stable alkaline anion exchange membranes (AAEMs) based on 1,2-dimethylimidazolium (proved to be much more stable than C2-unsubstituted imidazolium cation) were prepared by a hot-pressing method. The properties of these membranes, e.g., water uptake, swelling degree, ion-exchange capacity, conductivity and thermal and chemical stability, were characterized systematically. The swelling degree of the membranes decreases with the decrease of the amount of 1,2-dimethylimidazolium salt, up to 5.8%. The membranes are thermally stable below 200 °C. Alkaline direct methanol fuel cell (ADMFC) fabricated by using CoOx/C as the cathode catalyst and PtRu/C as the anode catalyst presents a promising performance with the peak power density of 12.7 mW cmâ2 at a current density of 45 mA cmâ2, indicating that the 1,2-dimethylimidazolium-functionalized AAEMs are promising for the application in ADMFCs.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 40, Issue 5, 9 February 2015, Pages 2363-2370
Journal: International Journal of Hydrogen Energy - Volume 40, Issue 5, 9 February 2015, Pages 2363-2370
نویسندگان
Congrong Yang, Suli Wang, Luhua Jiang, Jinbo Hu, Wenjia Ma, Gongquan Sun,