کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7717501 | 1497476 | 2014 | 12 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Co@Ru nanoparticle with core-shell structure supported over γ-Al2O3 for Fischer-Tropsch synthesis
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Co@Ru nanoparticle with core-shell structure supported over γ-Al2O3 for Fischer-Tropsch synthesis Co@Ru nanoparticle with core-shell structure supported over γ-Al2O3 for Fischer-Tropsch synthesis](/preview/png/7717501.png)
چکیده انگلیسی
Co@Ru/γ-Al2O3 core-shell structure catalysts with Co/Ru different weight ratios are successfully prepared via surface displacement reaction. This novel route including reduction of Co core by NaBH4 on the surface of γ-Al2O3 and then substitution of Co species with Ru species, the resultant of reduction of RuCl3 precursor with N2H4. These catalysts are characterized with techniques X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDX), high resolution transmission electron microscopy (HRTEM), N2 adsorption/desorption (BET), temperature programmed reduction (TPR), X-ray photoelectron spectroscopy (XPS) and Fourier transform infra-red (FTIR) of CO adsorbed. The characterization results confirm a uniform dispersion of Co@Ru nanoparticles with core-shell structure over γ-Al2O3. The core-shell Co@Ru/γ-Al2O3 catalysts show the remarkable catalytic activity towards Fischer-Tropsch synthesis (FTS) in comparison with Co/γ-Al2O3, which is related to special core-shell structure. These catalysts exhibited excellent abilities in the cases of increasing formation of long-chain hydrocarbons and suppressing selectivity to lighter hydrocarbons.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 39, Issue 33, 11 November 2014, Pages 18882-18893
Journal: International Journal of Hydrogen Energy - Volume 39, Issue 33, 11 November 2014, Pages 18882-18893
نویسندگان
Ali Haghtalab, Amir Mosayebi,