کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7719258 | 1497493 | 2014 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Hydrogen uptake of reduced graphene oxide and graphene sheets decorated with Fe nanoclusters
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Hydrogen uptake of reduced graphene oxide and graphene sheets decorated with Fe nanoclusters Hydrogen uptake of reduced graphene oxide and graphene sheets decorated with Fe nanoclusters](/preview/png/7719258.png)
چکیده انگلیسی
Graphene oxide (GO) has been prepared by employing modified Staudenmaier's method through thermal exfoliation of graphite oxide. High pressure hydrogen sorption isotherms up to 50Â bar of GO, reduced by thermal reduction (TR-GO), chemical reduction (CR-GO) and graphene sheets decorated with Fe nanoclusters (Fe-GS) have been investigated. Thermal reduction of GO at 623Â K under high vacuum yields TR-GO. Chemical reduction of GO using hydrazine forms CR-GO. Fe-GS was synthesized through arc-discharge between the ends of two graphite rods with one rod carrying Fe nanoparticles. The surface areas of these graphene samples were determined from the nitrogen adsorption isotherm employing Brunauer, Emmett and Teller (BET) method. Kelvin's equation was used to determine the pore size distribution of all graphene based samples. Hydrogen pressure-composition isotherms (PCI) were determined at 300Â K and at 77Â K, between 0.1 and 50Â bar. Further, in this paper, we present a comparative adsorption isotherm analysis of hydrogen and helium on TR-GO. This reveals that the volume of hydrogen and helium adsorbed by TR-GO is nearly equal. The similar uptake volume determined for both hydrogen and helium indicates the possibility of monolayer adsorption of hydrogen and also nearly similar binding energy between TR-GO and H2/He.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 39, Issue 16, 27 May 2014, Pages 8311-8320
Journal: International Journal of Hydrogen Energy - Volume 39, Issue 16, 27 May 2014, Pages 8311-8320
نویسندگان
M. Sterlin Leo Hudson, Himanshu Raghubanshi, Seema Awasthi, T. Sadhasivam, Ashish Bhatnager, Satoru Simizu, S.G. Sankar, O.N. Srivastava,