کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7719369 | 1497494 | 2014 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Thermogravimetric study on the pressurized hydropyrolysis kinetics of a lignite coal
ترجمه فارسی عنوان
مطالعه حرارتی سنجی بر روی سینتیک فشار هیدروپرولیز زغال سنگ قهوه ای
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کلمات کلیدی
هیدروپرولیز، ترموکوپل سه گانه سینتیک، زغال سنگ قهوه ای،
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
چکیده انگلیسی
Hydropyrolysis of coal is considered to be a third coal conversion technology between the coal liquification and gasification technologies. It is also the primary process for coal hydrogasification (CHG). However, the detailed kinetic characteristics of coal hydropyrolysis (CHP) are still rarely studied, which is adverse to the further development of the CHP and CHG technologies. In this work, the hydropyrolysis kinetics of a lignite coal is studied in a pressurized thermogravimetric analyzer (P-TGA). The non-isothermal thermogravimetric method is used and the effect of pressure on the pyrolysis kinetics of the lignite coal is detected. Finally, some useful results are found from the analyses for the lignite hydropyrolysis under P-TGA. With the increment of the pyrolysis pressure, the initial pyrolysis temperature increases when the pressure is higher than 1Â MPa; the temperature span of the pyrolysis process shrinks; the weight loss peak value position of the derivative thermogravimetric (DTG) curve shifts rightwards when the pressure is lower than 1Â MPa, while it shifts leftwards when the pyrolysis pressure is higher than 1Â MPa; the reaction process will be restrained when the pressure is lower than 2Â MPa. In addition, the kinetic triplets including the pre-exponential factor, the activation energy and the kinetic mechanism function are defined for the hydropyrolysis process under different pressures.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 39, Issue 15, 15 May 2014, Pages 7826-7833
Journal: International Journal of Hydrogen Energy - Volume 39, Issue 15, 15 May 2014, Pages 7826-7833
نویسندگان
Linbo Yan, Boshu He, Tianyi Hao, Xiaohui Pei, Xusheng Li, Chaojun Wang, Zhipeng Duan,