کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7720775 | 1497503 | 2014 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Investigation of plasticized UV-curable glycidyl methacrylate based solid polymer electrolyte for photoelectrochemical cell (PEC) application
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Investigation of plasticized UV-curable glycidyl methacrylate based solid polymer electrolyte for photoelectrochemical cell (PEC) application Investigation of plasticized UV-curable glycidyl methacrylate based solid polymer electrolyte for photoelectrochemical cell (PEC) application](/preview/png/7720775.png)
چکیده انگلیسی
A free standing electrolyte film containing poly glycidyl methacrylate (PGMA) as polymer host, lithium perchlorate (LiClO4) as charge carrier and ethylene carbonate (EC) as plasticizer were successfully prepared with solution casting technique. Nuclear magnetic resonance spectroscopy (NMR) was used to investigate the chemical structure of the polymer. The analyses of polymer electrolytes were performed by impedance spectroscopy (EIS), linear sweep voltammetry (LSV) and fourier transform infrared spectroscopy (ATR-FTIR). The solid polymer electrolyte exhibited the highest conductivity at room temperature and 373Â K with the values of 3.4Â ÃÂ 10â4Â SÂ cmâ1 and 1.2Â ÃÂ 10â3Â SÂ cmâ1 at 80Â wt.% of EC, respectively, in the presence of 80Â wt.% of EC. FTIR spectroscopy analysis confirmed the interaction between lithium salt and oxygen atoms in polymer host in the presence of EC. Moreover, the electrolytes containing EC showed good electrochemical stability (â1500 to 3000) mV which reveals the potential of this polymer electrolyte for photoelectrochemical cell (PEC) application.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 39, Issue 6, 14 February 2014, Pages 3018-3024
Journal: International Journal of Hydrogen Energy - Volume 39, Issue 6, 14 February 2014, Pages 3018-3024
نویسندگان
M. Imperiyka, A. Ahmad, S.A. Hanifah, N.S. Mohamed, M.Y.A. Rahman,