کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7721656 | 1497516 | 2013 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Roles of organic acids during exectrooxidation reaction over Pt-supported carbon electrodes in direct methanol fuel cells
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Roles of organic acids during exectrooxidation reaction over Pt-supported carbon electrodes in direct methanol fuel cells Roles of organic acids during exectrooxidation reaction over Pt-supported carbon electrodes in direct methanol fuel cells](/preview/png/7721656.png)
چکیده انگلیسی
A comprehensive study has been made to explore the role of organic acids on electrocatalytic performances of platinum (Pt) nanoparticles supported on carbon porous materials (CPMs) in proton exchange membrane fuel cells (PEMFCs). In particular, the effects of carboxylic acids (R-COOH), viz. formic acid, acetic acid, propionic acid, and butyric acid on catalytic activity, stability, and durability of anodic Pt/CPM electrocatalyst in direct methanol fuel cells (DMFCs) were investigated. In the presence of doped carboxylic acids, the electrooxidative activity of Pt/CPM follows the trend: HCOOHÂ <Â CH3COOHÂ <Â C2H5COOH <Â C3H7COOH, revealing a consistent increase in the severity of catalyst deactivation with the number of carbons on the alkyl chain of the dopant. The Pt/CPM was found to exhibit electrocatalytic performances and tolerance for poisoning than a commercial Pt/XC-72 catalyst with a similar Pt loading (20Â wt%). Moreover, a notable increase in mass activity up to ca. 150% over the spent Pt/CPM catalyst was observed up on removing the organic acid in the feed stream, indicating that catalyst poisoning by deactivation may be revived, even to its “intrinsic” activity.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 38, Issue 29, 30 September 2013, Pages 12984-12990
Journal: International Journal of Hydrogen Energy - Volume 38, Issue 29, 30 September 2013, Pages 12984-12990
نویسندگان
Chee Yong Wong, Shi-Kun Chen, An-Ya Lo, Chuan-Ming Tseng, Chiu-Yue Lin, Shang-Bin Liu,