کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7722673 | 1497525 | 2013 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Improvement of hydrogen-separating performance by on-stream catalytic cracking of silane over hollow fiber MFIÂ zeolite membrane
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
MFI zeolite membranes were synthesized on porous α-alumina hollow fibers by in-situ hydrothermal synthesis. The membranes were further modified for H2 separation by on-stream catalytic cracking deposition of methyldiethoxysilane (MDES) in the zeolitic pores. The separation performance of the modified membranes was characterized by separation of H2/CO2 gas mixture at 500 °C. Activation of MFI zeolite membranes by air at 500 °C was found to promote catalytic cracking deposition of silane in the zeolitic pores effectively, which resulted in significant improvement of H2-separating performance. The H2/CO2 separation factor of 45.6 with H2 permeance of 1.0 Ã 10â8 mol mâ2 sâ1 Paâ1 was obtained at 500 °C for a modified hollow fiber MFI zeolite membrane. The as-made membranes showed good thermochemical stability for the separation of H2/CO2 gas mixture containing H2O and H2S, respectively.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Hydrogen Energy - Volume 38, Issue 20, 9 July 2013, Pages 8409-8414
Journal: International Journal of Hydrogen Energy - Volume 38, Issue 20, 9 July 2013, Pages 8409-8414
نویسندگان
Zhou Hong, Feng Sun, Dongdong Chen, Chun Zhang, Xuehong Gu, Nanping Xu,