Nickel-based perovskite catalysts with iron-doping via self-combustion for hydrogen production in auto-thermal reforming of Ethanol

► A solid solution of La(Ni, Fe)O3 formed in the perovskite structure. ► Iron is reducible in La(Ni, Fe)O3 and forms the iron-nickel alloy. ► Iron improved the H2 yield in LaNiO3 and stability was observed in the 30-h ATR test.