کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7725037 | 1497841 | 2018 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Preparation of double-shell Co9S8/Fe3O4 embedded in S/N co-decorated hollow carbon nanoellipsoid derived from Bi-Metal organic frameworks for oxygen evolution reaction
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
Metal organic frameworks (MOFs) based catalysts are the most promising candidates for electrocatalytic reaction. Herein, we describe a fast, cost-effective and efficient method to construct an oxygen evolution electrocatalyst with a “bivalve hollow nanoellipsoid” structure, namely three dimensional (3D) bi-shells Co9S8/Fe3O4 embedded in S/N co-decorated hollow carbon nanoellipsoid (H-Co9S8/Fe3O4@SNC). The bivalve metallic compounds hollow structure decreases the proton-electron transfer kinetics on carbon nanoellipsoid, and promoting the oxygen evolution reaction (OER). Specifically, the H- Co9S8/Fe3O4@SNC reveals an excellent catalytic activity with a low overpotential of 280â¯mVâ¯at the current density of 10â¯mAâ¯cmâ2 and a small Tafel slope of 87â¯mV decâ1. Moreover, this H-Co9S8/Fe3O4@SNC electrode is applied to rotating ring-disk electrode (RRDE) and show remarkable catalytic stability and give â¼97.5% Faradic efficiency toward OER via chronoamperometric measurement at a rotation rate of 1600â¯rpm. Following that, the mechanism is investigated and reveal the excellent catalytic activity is mainly owed to the hollow structure and the catalytic synergistic effects of the double shell Co9S8/Fe3O4, simultaneously, the introduction of oxygen vacancy during the pyrolysis process to the formation of Fe3O4.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 391, 1 July 2018, Pages 59-66
Journal: Journal of Power Sources - Volume 391, 1 July 2018, Pages 59-66
نویسندگان
Lang Gan, Jing Fang, Mengran Wang, Langtao Hu, Kai Zhang, Yanqing Lai, Jie Li,