کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7726610 | 1497861 | 2017 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Tailoring the activity via cobalt doping of a two-layer Ruddlesden-Popper phase cathode for intermediate temperature solid oxide fuel cells
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Tailoring the activity via cobalt doping of a two-layer Ruddlesden-Popper phase cathode for intermediate temperature solid oxide fuel cells Tailoring the activity via cobalt doping of a two-layer Ruddlesden-Popper phase cathode for intermediate temperature solid oxide fuel cells](/preview/png/7726610.png)
چکیده انگلیسی
Co-doped La3Ni2O7 single phase mix-conductors are successfully fabricated and investigated as cathodes for solid oxide fuel cells. Electrochemical measurement suggests that the polarization resistance of the cell using such cathodes reduce largely when increasing the Co content in La3Ni2O7 cathodes, which is about 1.12 Ω cm2 for La3Ni1.9Co0.1O7 and 0.35 Ω cm2 for La3Ni1.6Co0.4O7 both measured at 650 °C. X-ray photoelectron spectroscopy analysis suggests that the Co-doped La3Ni2O7 samples keep much more oxygen vacancies at high temperatures when compared with those undoped samples, which can benefit both oxygen adsorption and oxygen ion diffusion process in the oxygen reduction reaction. Moreover, both conductivity and magnetic measurements indicate that the covalence of B-O bonds in Co-doped samples can be largely improved because of the more localized 3d electrons in the Co substituted samples, which can further help to accelerate the proton diffusion process. The findings in this research demonstrate that the Co-doped La3Ni2O7 with the two-layer structure can be a promising cathode for proton conducting SOFCs, due to its high activity toward the oxygen reduction reaction.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 371, 15 December 2017, Pages 41-47
Journal: Journal of Power Sources - Volume 371, 15 December 2017, Pages 41-47
نویسندگان
Zezhi Chen, Jianlin Wang, Daoming Huan, Shujie Sun, Guopeng Wang, Zhengping Fu, Wenhua Zhang, Xusheng Zheng, Haibin Pan, Ranran Peng, Yalin Lu,