کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7727122 1497904 2016 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Glass-ceramic sealant for solid oxide fuel cells application: Characterization and performance in dual atmosphere
ترجمه فارسی عنوان
سیلانت شیشه ای سرامیکی برای استفاده از سلول های سوختی اکسید جامد: ویژگی ها و عملکرد در فضای دوگانه
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
چکیده انگلیسی
A glass-ceramic composition was designed and tested for use as a sealant in solid oxide fuel cell (SOFC) planar stack design. The crystallization behaviour was investigated by calculating the Avrami parameter (n) and the activation energy for crystallization (Ec) was obtained. The calculated values for n and Ec were 3 and 413.5 kJ/mol respectively. The results of thermal analyses indicate that this composition shows no overlap between the sintering and crystallization stages and thus an almost pore-free sealant can be deposited and sintered at 850 °C in air for 30 min. A gas tightness test has been carried out at 800 °C for 1100 h in dual atmosphere (Ar-H2 and air) without recording any leakage. Morphological and crystalline phase analyses were conducted prior and following tests in dual atmospheres in order to assess the compatibility of the proposed sealant with the metallic interconnect.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 328, 1 October 2016, Pages 262-270
نویسندگان
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