کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7727229 | 1497906 | 2016 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Sustainable AC/AC hybrid electrochemical capacitors in aqueous electrolyte approaching the performance of organic systems
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A high energy hybrid AC/AC electrochemical capacitor has been realized in aqueous Li2SO4+KI electrolyte mixture. Owing to the redox processes associated with the 2Iâ/I2 system, the positive electrode operates in narrow potential range and displays high capacity. During prolonged potentiostatic floating at 1.6 V, the hybrid cell demonstrates remarkably stable capacitance and resistance. Analyses by temperature programmed desorption after floating at 1.6 V proved that oxidation of the positive AC electrode is prevented by the use of Li2SO4+KI, which enables the maximum potential of this electrode to be shifted below the water oxidation potential. When charged at 0.2 A gâ1 up to U = 1.6 V, the hybrid cell displays a high capacitance of 75 F gâ1 (300 F gâ1 per mass of one electrode) compared to 47 F gâ1 (188 F gâ1 per mass of one electrode) for a symmetric cell in Li2SO4. At 0.2 A gâ1 up to 1.6 V, the hybrid capacitor in Li2SO4+KI displays an energy density of 26 Wh kgâ1 which approaches the energy density of 30.9 Wh kgâ1 measured when the same carbon is implemented in a capacitor using TEABF4/ACN electrolyte and charged up to 2.5 V.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 326, 15 September 2016, Pages 652-659
Journal: Journal of Power Sources - Volume 326, 15 September 2016, Pages 652-659
نویسندگان
Qamar Abbas, Paulina Babuchowska, Elżbieta FrÄ
ckowiak, François Béguin,