کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7730924 | 1497938 | 2015 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A polytetrafluoroethylene porous membrane and dimethylhexadecylamine quaternized poly (vinyl benzyl chloride) composite membrane for intermediate temperature fuel cells
ترجمه فارسی عنوان
یک غشای متخلخل پلی تترافلوواتو اتیلن و دی اتیل هگزادسیلامین کواترنیزه پلاستیک (وینیل بنزیل کلرید) غشاء کامپوزیت برای سلول های سوخت متوسط دما
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
چکیده انگلیسی
A composite material for phosphoric acid (PA) loaded membrane was prepared using a porous polytetrafluoroethylene (PTFE) thin film. N, N-Dimethylhexadecylamine partially quaternized poly (vinyl benzyl chloride) (qPVBzClâ) was synthesized as the substrate for the phosphoric acid loaded polymer membrane. SEM observation indicated that the pores were filled with the qPVBzClâ. The maximum PA loading level was calculated to be 4.67-5.12 per repeat unit on average. TGA results showed that resultant composite membrane was stable in the intermediate temperature from 100 °C to 200 °C. The composite membrane tensile stress was 56.23 MPa, and the Young's Modulus was 0.25 GPa, and the fractured elongation was 23%. The conductivity of the composite membrane after the PA addition (H3PO4@PTFE/qPVBzClâ) increased from 0.085 S cmâ1 to 0.11 S cmâ1 from 105 °C to 180 °C. The peak power density of the H2/O2 at 175 °C under low humidity condition (<1%) for H3PO4@PTFE/qPVBzClâ membranes was 360 mW cmâ2.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 294, 30 October 2015, Pages 691-695
Journal: Journal of Power Sources - Volume 294, 30 October 2015, Pages 691-695
نویسندگان
Yuan-Cheng Cao, Chenxi Xu, Linling Zou, Keith Scott, Jiyan Liu,