کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7731560 | 1497939 | 2015 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Microporous La0.8Sr0.2MnO3 perovskite nanorods as efficient electrocatalysts for lithium-air battery
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Efficient electrocatalyst for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) is the most critical factor to influence the performance of lithium-air batteries. We present La0.8Sr0.2MnO3 (LSM) perovskite nanorods as high active electrocatalyst fabricated via a soft template method for lithium-air batteries. The as-prepared LSM nanorods are microporous with numerous defects and large surface area (20.6 m2 gâ1), beneficial to the ORR and OER in the discharge and charge processes, respectively. Lithium-air batteries based on the microporous LSM nanorods electrocatalysts show enhanced electrochemical performances, including high first discharge specific capacity (6890 mAh gâ1(electrode) at 200 mA gâ1), low overpotential, good rate capability (up to 400 mA gâ1), and cycle stability (only 1.1% voltage loss after 30 circles of specific capacity limit of 1000 mAh gâ1 tested at 200 mA gâ1). The improved performance might be due to the synergistic effect of the unique microporous and one-dimensional structure and numerous defects of the prepared LSM catalyst.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 293, 20 October 2015, Pages 726-733
Journal: Journal of Power Sources - Volume 293, 20 October 2015, Pages 726-733
نویسندگان
Fanliang Lu, Yarong Wang, Chao Jin, Fan Li, Ruizhi Yang, Fanglin Chen,