کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7734569 | 1497954 | 2015 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Preparation of microporous carbon nanofibers from polyimide by using polyvinyl pyrrolidone as template and their capacitive performance
ترجمه فارسی عنوان
تهیه نانو فیبرهای کربنی مینورپور از پلی آمید با استفاده از پلی وینیل پیرولیدون به عنوان الگو و عملکرد خازنی آنها
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
چکیده انگلیسی
A self-supported and binder-free micro-porous polyimide (PI)-based carbon fibers are prepared by polymer blend electrospinning technology and subsequent thermal treatment without activation and evaluated electrochemically for supercapacitor application. Polyvinyl pyrrolidone (PVP) is successfully used as a pore forming template by controlling the crosslinking between PVP and PI precursor via imidization process. The maximal specific capacitance of 215 F gâ1 based on a symmetrical two-electrode supercapacitor is achieved at 0.2 A gâ1. The specific capacitance could still remain 113 F gâ1 at 100 A gâ1 with the retention ratio of 53%. It is noteworthy to mention that the energy density is 7.5 Wh kgâ1 with power density of 0.05 kW kgâ1 at a current density of 0.2 A gâ1, and 5.0 Wh kgâ1 with a high power density of 7.5 kW kgâ1 at 30.0 A gâ1. The maximum power density is 20.0 kW kgâ1 with energy density of 3.0 Wh kgâ1. The results indicate that the specific capacitance is not only attributed to optimized pore structures and surface chemistry but also attributed to the wettability of the electrolyte. The improved rate performance should be related to the reduced ion transportation distance derived from the nanofibers.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 278, 15 March 2015, Pages 683-692
Journal: Journal of Power Sources - Volume 278, 15 March 2015, Pages 683-692
نویسندگان
TrungHieu Le, Ying Yang, Zhenghong Huang, Feiyu Kang,