کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7735364 | 1497961 | 2014 | 20 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Modified pulse electrodeposition of Pt nanocatalyst as high-performance electrode for PEMFC
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
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چکیده انگلیسی
Low platinum loading electrode was successfully deposited by a modified pulse galvanic signal in H2PtCl6 electrolyte using carbon black as support directly on a GDL (Gas Diffusion Layer). SEM images of the deposition were composed by rough Pt particles of 50 nm leading to specific electrochemical surface area of 53 m2 gâ1. In spite of large particle size and a low cathode loading of 0.12 mg cmâ2, the proton exchange membrane fuel cell (PEMFC) fed with humidified H2 and O2 at 80 °C, 1.5 absolute bar reached 0.2 mA cmPtâ2 and 0.1 A mgâ1 at 0.9 VIR-free which were twice higher than a reference membrane electrodes assembly (MEA) with a cathode loaded at 0.4 mgPt.cmâ2. Such an active cathode electrode may be ascribed to a higher utilization rate of the platinum caused by an efficient catalyst deposition by electrochemical route.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 271, 20 December 2014, Pages 401-405
Journal: Journal of Power Sources - Volume 271, 20 December 2014, Pages 401-405
نویسندگان
F. Fouda-Onana, N. Guillet, A.M. AlMayouf,