کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7739763 | 1497993 | 2013 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Preparation of graphene-supported platinum nanoparticles in aqueous solution by femtosecond laser pulses for methanol oxidation
ترجمه فارسی عنوان
آماده سازی نانوذرات پلاتین تحت حمایت گرافن در محلول آبی با استفاده از پالسهای لیزر فموتوسجد برای اکسیداسیون متانول
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کلمات کلیدی
سلول سوختی، لیزر فموستیک گرافن، نانوذرات پلاتین،
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
چکیده انگلیسی
A simple and rapid approach for the deposition of platinum (Pt) nanoparticles onto surface of graphene in aqueous solution without reducing agents by femtosecond laser pulses is demonstrated. The formation of graphene-supported Pt in aqueous solution is confirmed by a variety of means such as ultraviolet-visible absorption spectroscopy, transmission electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. Graphene oxide and PtCl62â are simultaneously reduced and Pt nanoparticles can be deposited on the surface of graphene. The presence of Pt on graphene is further confirmed by cyclic voltammetry. The value of electrochemically active surface area of the prepared graphene-supported Pt (58.9Â m2Â gâ1) is higher than most previously reported preparation methods for graphene-supported Pt. For the electrochemical oxidation of methanol, the prepared graphene-supported Pt exhibits a mass activity of 295Â mAÂ mgâ1 at 0.669Â V, which was higher than commercial Pt catalyst and graphene-supported Pt prepared by electrochemical method.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 239, 1 October 2013, Pages 164-168
Journal: Journal of Power Sources - Volume 239, 1 October 2013, Pages 164-168
نویسندگان
Han-Wei Chang, Yu-Chen Tsai, Chung-Wei Cheng, Cen-Ying Lin, Ping-Han Wu,