کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7740351 | 1497990 | 2013 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Single-crystalline Li4Ti5O12 nanorods and their application in high rate capability Li4Ti5O12/LiMn2O4 full cells
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Single-crystalline Li4Ti5O12 nanorods have been successfully prepared through a molten salt method, followed by a precipitation method, and characterized with X-ray powder diffractometry, field-emission scanning electron microscopy, and transmission electron microscope. Their electrochemical properties have been studied by charge/discharge cycling and cyclic voltammetry. The results show that the single-crystalline Li4Ti5O12 nanorods reveal high capacity, excellent rate capability and cycle stability. The discharge capacity up to 176.4 mAh gâ1 at 0.1 C rate is achieved. When tested at 10 C rate, the first discharge capacity reaches 135.9 mAh gâ1, and the capacity retention is more than 61.5% after 1500 cycles. Furthermore, high rate capability Li4Ti5O12/LiMn2O4 full cells have been made using Li4Ti5O12 nanorods as the negative electrode, which display superior cycle stability at high rate. The discharge capacity and the mass energy density sequentially reach 40 mAh gâ1 and 86.4 Wh kgâ1 at 10 C rate, while the capacity retention is about 60% after 1000 cycles.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 242, 15 November 2013, Pages 222-229
Journal: Journal of Power Sources - Volume 242, 15 November 2013, Pages 222-229
نویسندگان
Liu Jiang Xi, Hong Kang Wang, Shi Liu Yang, Ru Guang Ma, Zhou Guang Lu, Chen Wei Cao, Kwan Lan Leung, Jian Qiu Deng, Andrey L. Rogach, C.Y. Chung,