کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7743832 | 1498024 | 2012 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Electrochemical in situ polymerization of reduced graphene oxide/polypyrrole composite with high power density
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
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چکیده انگلیسی
We demonstrate a novel method of in situ galvanostatic polymerization to prepare reduced graphene oxide (RGO)/polypyrrole composite (RGO-PPy) for supercapacitors electrode. The PPy and the RGO interact closely and form the composite with porous structure. The BET specific surface area of RGO-PPy reaches 108 m2 gâ1. The RGO-PPy composites show the high protonation level on polypyrrole (PPy) ring (41.1%), which can be related to the doping of PPy by oxygen-containing groups in RGO sheet. The RGO-PPy electrodes exhibit good electrochemical performance. The specific capacitance of RGO-PPy electrodes still reaches 224 F gâ1 at charge/discharge current density of 240 A gâ1 within an electrochemical windows of 0.8 V in 3 M KCl aqueous solution. The specific power of RGO-PPy electrodes reaches 38.6 kW kgâ1 when its specific energy reaches 2.5 Wh kgâ1 in two-electrode cell. The RGO-PPy electrodes have good cycle stability and show less than 17% specific capacitance decay at a charge/discharge current of 30 A gâ1 within an electrochemical windows of 0.8 V after 5000 cycles.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 208, 15 June 2012, Pages 138-143
Journal: Journal of Power Sources - Volume 208, 15 June 2012, Pages 138-143
نویسندگان
Jingping Wang, Youlong Xu, Jianbo Zhu, Penggang Ren,