کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7744204 | 1498219 | 2018 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Insight into the dehydration behaviour of scandium-substituted barium titanate perovskites via simultaneous in situ neutron powder thermodiffractometry and thermogravimetric analysis
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Hydration-dehydration cycles are critical to the mechanical performance of ceramic proton conductors. The development of in situ methods is desirable in order to study their structural response under conditions that mimic the operating ones. Neutron powder diffraction studies combined with simultaneous thermogravimetric analysis were performed on the hydrated forms of two members of the oxygen deficient perovskite BaTi1âxScxO3âδ series, with xâ¯=â¯0.5 and xâ¯=â¯0.7. Rietveld analyses agreed with in situ gravimetric data, allowing correlation of occupancy factors of the oxygen site to hydration levels and other structural data. Dehydration is an activated process that impacts on structural parameters and the level of Sc substitution was found to control the structural response during in situ dehydration, with higher Sc content leading to significantly greater volume contraction. This was rationalised by the chemical expansion due to hydration of oxygen vacancies within the xâ¯=â¯0.5 sample being anomalously small. Furthermore, the behaviour of the xâ¯=â¯0.5 system revealed an unexpected cell expansion during the early stages of dehydration, suggesting the hydration level may influence the thermal expansion coefficient (TEC).
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Ionics - Volume 324, 15 October 2018, Pages 233-240
Journal: Solid State Ionics - Volume 324, 15 October 2018, Pages 233-240
نویسندگان
Nico Torino, Paul F. Henry, Christopher S. Knee, Samantha K. Callear, Ronald I. Smith, Seikh M.H. Rahman, Sten G. Eriksson,