کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7745009 | 1498255 | 2016 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
SrCo1 â xMoxO3 â δ perovskites as cathode materials for LaGaO3-based intermediate-temperature solid oxide fuel cells
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
SrCoO3 â δ is an important parent compound of functional materials. The structural instability limited its applications as intermediate-temperature solid oxide fuel cell (IT-SOFC) cathode materials. Here we reported the performances of SrCo1 â xMoxO3 â δ (SCM, x = 0.05-0.2) oxides with a tetragonal structure as potential cathode materials for IT-SOFCs based on La0.9Sr0.1Ga0.8Mg0.2O3 â δ (LSGM) electrolyte. The x = 0.05 sample was well crystallized in a single-phase tetragonal structure at room temperature, while impurity phase was observed in the x â¥Â 0.1 samples. The SCM exhibited a good chemical compatibility with the LSGM electrolyte at 950 °C for 10 h. The Mo doping for Co significantly improved the structural stability and electrical conductivity of the SCM materials. The area specific resistances of the x = 0.05 and 0.1 cathodes on the LSGM electrolyte were 0.069 and 0.079 Ω cm2 at 700 °C, respectively. The maximum power densities of the single-cells on a 300 μm-thick LSGM electrolyte reached 795 and 687 mW cmâ 2 at 800 °C for the x = 0.05 and 0.1 cathodes, respectively. The x = 0.05 composition is a promising candidate cathode for IT-SOFC application due to its good chemical compatibility, high conductivity and electrochemical performance.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Ionics - Volume 288, May 2016, Pages 32-35
Journal: Solid State Ionics - Volume 288, May 2016, Pages 32-35
نویسندگان
Rui Wang, Fangjun Jin, Le Ta, Tianmin He,