کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7745709 | 1498262 | 2015 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Improvement in hydrophobicity of olivine lithium manganese iron phosphate cathodes by SiF4 treatment for lithium-ion batteries
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
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چکیده انگلیسی
In this report, we successfully demonstrate a novel SiF4 treatment on lithium manganese iron phosphate cathode (LMFP) that can significantly improve its hydrophobic property. The effect of SiF4 treatment on the structure and hydrophobicity of LMFP powder was studied by X-ray diffraction, Fourier transform infra-red spectroscopy, scanning transmission electron microscopy-energy dispersive X-ray spectroscopy, Karl Fisher titration, and thermo-microbalance gravimetric studies. The SiF4 treated LMFP cathode shows a substantial decrease in moisture adsorption by up to half of the untreated LMFP under ambient conditions. The SiF4-treated LMFP also shows excellent cycle life when cycled in lithium-ion full cells, even after exposing the electrodes to ambient conditions for one day, while the untreated LMFP showed a decrease in cycle life after the same exposure.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Ionics - Volume 281, 15 November 2015, Pages 82-88
Journal: Solid State Ionics - Volume 281, 15 November 2015, Pages 82-88
نویسندگان
Murali G. Theivanayagam, Terry Hu, Robin Ziebarth, Stacie Santhany, Janet Goss, Hideaki Maeda, Avani Patel, Michael Behr, Michael Lowe, Anne Leugers,