کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7747154 | 1498314 | 2012 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis and Na+ conduction properties of Nasicon-type glass-ceramics in the system Na2O-Y2O3-X2O3-SiO2 (XÂ =Â B, Al, Ga) and effect of Si substitution
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Glass-ceramics of the boron-, aluminium- or gallium-containing Na5RSi4O12-type (R = rare earth; Y) Na+-superionic conductors were prepared by crystallization of glasses with the composition Na3 + 3x + yY1âxXySi3âyO9 (X = B; NaYBSi, X = Al; NaYAlSi, X = Ga; NaYGaSi) (x = 0.2, y = 0.1). The crystallization kinetics of the glasses was examined by DTA, and the effects of X elements on the separation of the phase and the microstructural effects on the conduction properties of glass-ceramics were discussed. The activation energies of crystal growth of the NaYBSi, NaYAlSi and NaYGaSi glasses with the Na3.7Y0.8B0.1Si2.9O9, Na3.7Y0.8Al0.1Si2.9O9 and Na3.7Y0.8 Ga0.1Si2.9O9 compositions were 410, 392 and 382 kJ/mol, respectively. The conductivities of the glass-ceramic NaYBSi, NaYAlSi and NaYGaSi were 4.32 Ã 10â 2, 3.73 Ã 10â 2 and 3.40 Ã 10â 2 S/cm at 300 °C, respectively.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Ionics - Volume 225, 4 October 2012, Pages 367-370
Journal: Solid State Ionics - Volume 225, 4 October 2012, Pages 367-370
نویسندگان
Toshinori Okura, Koji Kawada, Naoya Yoshida, Hideki Monma, Kimihiro Yamashita,