کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7750200 | 1499109 | 2018 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Examination of lutetium(III)-DOTA and copper(II)-NOTA solution structures using EXAFS
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Examination of lutetium(III)-DOTA and copper(II)-NOTA solution structures using EXAFS Examination of lutetium(III)-DOTA and copper(II)-NOTA solution structures using EXAFS](/preview/png/7750200.png)
چکیده انگلیسی
Targeted radionuclide therapy generally relies on the chelation of select short-lived isotopes such as 177Lu and 67Cu. The majority of Lu(III) and Cu(II) chelate structural information is derived from solid state diffraction data. Herein, the complexes Lu(DOTA)â, Cu(NOTA)â were examined in solution using EXAFS for the first time. Both ligands were fully deprotonated and coordinated to the metal with four and three carboxylic sites for Lu(DOTA)â and Cu(NOTA)â, respectively. Near-neighbor correlations from nitrogen atoms on the macrocyclic cages were also visible in the spectra in addition to the adjacent carbon backbones. Coordination numbers, bond distances, and Debye-Waller factors are reported and discussed alongside differences with known crystal structures.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 482, 1 October 2018, Pages 118-121
Journal: Inorganica Chimica Acta - Volume 482, 1 October 2018, Pages 118-121
نویسندگان
M. Alex Brown, Thomas Brossard, David A. Rotsch,