کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7751374 1499182 2013 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Stepwise formation of cyclodimer and cage via decomposition of hexafluorophosphate anion. Structures and related properties of (2,2′-bipyridine)palladium(II) complexes of 1,3,5-tris(nicotinoyloxyethyl)cyanurate
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Stepwise formation of cyclodimer and cage via decomposition of hexafluorophosphate anion. Structures and related properties of (2,2′-bipyridine)palladium(II) complexes of 1,3,5-tris(nicotinoyloxyethyl)cyanurate
چکیده انگلیسی
Reaction of (bpy)Pd(PF6)2 (bpy = 2,2′-bipyridine) with new tridentate ligand 1,3,5-tris(nicotinoyloxyethyl)cyanurate (L) allows to form amorphous microspheres consisting of [(bpy)Pd(L)]2(PF6)4. Recrystallization of amorphous microspheres yields single crystals consisting of [(bpy)3Pd3(μ3-HPO4)(L)](PF3(OH)3)·3F·15H2O, which can be induced from the decomposition of the PF6− anions. Alternatively, direct reactions of (bpy)Pd(PF6)2 with L in the presence of Na2HPO4 or Na2HAsO4 under reflux conditions produce the same single crystals in the form of cage molecules, [(bpy)3Pd3(μ3-HYO4)(L)](PF3(OH)3)·3F (Y = P, As).
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 405, 24 August 2013, Pages 9-14
نویسندگان
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