کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7751552 1499182 2013 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Solid state syntheses of nano lead(II) iodide triazole carboxylate coordination polymer from its bromide/thiocyanate/chloride analogs via mechanochemical crystal to crystal transformations
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Solid state syntheses of nano lead(II) iodide triazole carboxylate coordination polymer from its bromide/thiocyanate/chloride analogs via mechanochemical crystal to crystal transformations
چکیده انگلیسی
Irreversible crystal-to-crystal transformations of 3D lead(II) coordination polymers with the ligand 1H-1,2,4-triazole-3-carboxylic acid (HL), [Pb(L)(μ2-Br)(H2O)]n (1), [Pb(L)(μ1,1-NCS)(H2O)]n (2) and [Pb(L)(μ2-Cl)(H2O)]n (3) to [Pb(L)(μ2-I)]n (4) by solid state anion-replacement processes, have been studied. Nanoparticles of compounds 1 and 2 were synthesized by sonochemical process. The SEM images showed that no morphology change occurs during anion-replacements of nanocrystals.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganica Chimica Acta - Volume 405, 24 August 2013, Pages 203-208
نویسندگان
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