Diphosphine-induced thiolate-bridge scission of [Re(CO)3(μ,κ2-S,N-thpymS)]2 (thpymS = 1,4,5,6-tetrahydropyrimidine-2-thiolate): Structural and computational studies of configurational isomers of [Re(CO)3(κ2-S,N-thpymS)]2(μ,κ1,κ1-dppe)

The reactions of binuclear [Re(CO)3 (μ,κ2-S,N-thpymS)]2 with diphosphines have been investigated which led to the isolation and characterization of a range of different products.140