کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7791099 | 1500645 | 2014 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Crosslinked bicontinuous biobased PLA/NR blends via dynamic vulcanization using different curing systems
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Crosslinked bicontinuous biobased PLA/NR blends via dynamic vulcanization using different curing systems Crosslinked bicontinuous biobased PLA/NR blends via dynamic vulcanization using different curing systems](/preview/png/7791099.png)
چکیده انگلیسی
In this study, blends of entirely biosourced polymers, namely polylactide (PLA) and natural rubber (NR), were prepared through dynamic vulcanization using dicumyl peroxide (DCP), sulphur (S) and phenolic resin (2402) as curing agents, respectively. The crosslinked NR phase was found to be a continuous structure in all the prepared blends. The molecular weight changes of PLA were studied by gel permeation chromatography. Interfacial compatibilization between PLA and NR was investigated using Fourier transform infrared spectroscopy and scanning electron microscopy. The thermal properties of blends were evaluated by differential scanning calorimetry and thermogravimetric analysis instrument. It was found that the molecular weight of PLA and interfacial compatibilizaion between PLA and NR showed a significant influence on the mechanical and thermal properties of blends. The PLA/NR blend (60/40 w/w) by DCP-induced dynamic vulcanization owned the finest mechanical properties and thermal stability.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Carbohydrate Polymers - Volume 113, 26 November 2014, Pages 438-445
Journal: Carbohydrate Polymers - Volume 113, 26 November 2014, Pages 438-445
نویسندگان
Daosheng Yuan, Kunling Chen, Chuanhui Xu, Zhonghua Chen, Yukun Chen,