کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7791939 1500651 2014 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Use of chloromethylstyrene as a supporter for convenient preparation of carbohydrate monomer and glycopolymers
ترجمه فارسی عنوان
استفاده از کلر متیل استایرن به عنوان یک پشتیبان برای آماده سازی مناسب مونومر و گلیکوپلیمرهای کربوهیدرات
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
چکیده انگلیسی
A convenient access for glycopolymers was accomplished by using a styrene-modified glycomonomer, which was prepared from chloromethylstyrene as a key starting material and N-acetyl-d-glucosamine (GlcNAc) as a model carbohydrate. One-step conversion of the styrene derivative gave an azidostyrene, which was treated with a propargyl GlcNAc to afford a carbohydrate monomer after deprotection in good yield. The water-soluble GlcNAc monomer was polymerized with or without acrylamide to give the corresponding white powdery glycopolymers, which were evaluated for their interaction against wheat germ agglutinin (WGA) on the basis of fluorescence change of tryptophan in WGA.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Carbohydrate Polymers - Volume 107, 17 July 2014, Pages 209-213
نویسندگان
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