کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7825247 | 1502923 | 2018 | 30 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Relations between morphology and micromechanical properties of alpha, beta and gamma phases of iPP
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آلی
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
The relations between crystalline structure and micromechanical properties of α-, β- and γ-phase of isotactic polypropylene (iPP) were investigated. The iPP samples with various crystalline phase compositions were prepared by a controlled high-pressure crystallization that enabled us to obtain not only α-iPP and β-iPP modifications, but also a series of almost pure γ-iPP samples with gradually changing morphology, crystallinity and lamellar thickness. The micromechanical properties were assessed by instrumented microindentation hardness testing (MHI), from which we determined indentation hardness (HIT), indentation modulus (EIT), indentation creep (CIT) and elastic part of the indentation work (ηIT). It was demonstrated that γ-iPP does not necessarily exhibit better mechanical performance than α- and β-iPP, as suggested by some previous studies, because the final properties are strongly influenced not only by the phase composition (i.e. by the content of α-, β- and γ-phase), but also by the overall crystallinity.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polymer Testing - Volume 67, May 2018, Pages 522-532
Journal: Polymer Testing - Volume 67, May 2018, Pages 522-532
نویسندگان
Miroslav Slouf, Ewa Pavlova, Sabina Krejcikova, Aleksandra Ostafinska, Alexander Zhigunov, Vladislav Krzyzanek, Przemyslaw Sowinski, Ewa Piorkowska,