کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7833153 | 1503517 | 2018 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Structural evolution of oxidized surface of zirconium-silicide under ion irradiationm
ترجمه فارسی عنوان
تکامل ساختاری سطح اکسید شده زیرکونیوم سیلیکید تحت اشعه یون
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
چکیده انگلیسی
Irradiation-induced structural evolution and compositional alterations on nanometer length scales of ZrO2-SiO2 nanocomposite and crystalline ZrSiO4, produced by oxidation of ZrSi2 at 1000â¯Â°C and 1400â¯Â°C, respectively, have been investigated. Irradiations were performed with 3.9â¯MeV Si2+ at 305â¯Â°C up to damage levels of 60 displacements per atom (dpa), and post-irradiation characterization was conducted by cross-sectional scanning- and transmission electron microscopy (STEM and TEM) in conjunction with energy dispersive spectroscopy (EDS), as well as glancing-angle X-ray diffraction (XRD). The multilayered nanocomposite oxide showed extensive phase mixing so that the originally distinct interfaces between ZrO2 and SiO2 phases were obliterated resulting in the formation of a single amorphous Zr-Si-O phase. Crystalline ZrSiO4 grains were completely amorphized at damage levels of 5-15â¯dpa, as evidenced by disappearance of grain boundaries and as confirmed by electron diffraction. The irradiation-induced phase transformation for both types of oxide structures has the potential to dramatically enhance corrosion resistance in high temperature aqueous and steam environments.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Surface Science - Volume 455, 15 October 2018, Pages 333-342
Journal: Applied Surface Science - Volume 455, 15 October 2018, Pages 333-342
نویسندگان
Hwasung Yeom, Li He, Robert Mariani, Kumar Sridharan,