کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7850003 | 1508845 | 2016 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Study of nitrogen-doped carbon nanomaterials by bomb calorimetry
ترجمه فارسی عنوان
بررسی نانو مواد کربن نیتروژن کربن با استفاده از کولورمتری بمب
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی انرژی
انرژی (عمومی)
چکیده انگلیسی
Nitrogen-doped carbon nanotubes (N-doped CNTs) and nitrogen-doped carbon nanoflakes (N-doped CNFs), which are promising materials for energy storage devices, were investigated by adiabatic bomb calorimetry method to determine their enthalpies of combustion (ÎcH0298) and of formation (ÎfH0298). All materials were characterized by elemental analysis, transmission and scanning electron microscopy, X-ray photoelectron, Raman spectroscopy as well as thermal analysis. The relationships between composition, nitrogen content and structure were studied. All ÎfH0298 values of the N-doped CNTs and CNFs were found to be negative and to decrease with the increase in nitrogen content. The value of ÎfH0298 of the N-doped CNTs changed from -(0.79 ± 0.01) to -(74.08 ± 0.15) kJ/mol with the increase in nitrogen content from 1.54 to 2.52 wt. % and that of N-doped CNFs changed from -(59.49 ± 0.30) to -(126.84 ± 1.16) kJ/mol with the increase in nitrogen content from 7.07 to 11.25 wt. %. The enthalpy of formation of carbon nanoflakes was -(29.78 ± 0.58) kJ/mol which is higher than that for N-doped CNFs.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Carbon - Volume 102, June 2016, Pages 506-512
Journal: Carbon - Volume 102, June 2016, Pages 506-512
نویسندگان
Evgeniya V. Suslova, Konstantin I. Maslakov, Serguei V. Savilov, Anton S. Ivanov, Li Lu, Valery V. Lunin,