کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7852622 | 1508868 | 2014 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Benzene diffusion on graphite described by a rough hard disk model
ترجمه فارسی عنوان
انتشار بنزن در گرافیت که توسط یک مدل دیسک سخت دیجیتال توصیف شده است
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی انرژی
انرژی (عمومی)
چکیده انگلیسی
New insight into the nature of diffusion and the origin of friction of a prototype system for weak physisorption - benzene molecules, C6H6, adsorbed on the basal plane (0Â 0Â 0Â 1) of graphite - has been obtained with quasi-elastic neutron scattering (QENS). Spectra were measured at relative adsorbate coverages between 0.1 and 1.0Â monolayers (ML) and at sample temperatures between 60Â K and 140Â K. Our experimental observations require a substantial modification of the model of interaction between benzene molecules and graphite surfaces: in contrast to recent studies we find only weak kinetic surface friction, but a substantial dissipative interaction during inter-molecular collisions. At coverages of up to 0.5Â ML the molecular dynamics are successfully modeled by a rough hard disk model, which we derive from a three-dimensional rough hard sphere model. At the full monolayer, three body and higher order collisions are dominant and the rough hard disk model breaks down, as expected.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Carbon - Volume 79, November 2014, Pages 183-191
Journal: Carbon - Volume 79, November 2014, Pages 183-191
نویسندگان
I. Calvo-Almazán, E. Bahn, M.M. Koza, M. Zbiri, M. Maccarini, M.T.F. Telling, S. Miret-Artés, P. Fouquet,