Photocatalytic hydrogen generation of ZnO rod-CdS/reduced graphene oxide heterostructure prepared by Pt-induced oxidation and light irradiation-assisted methods

A synthesis method including Pt-induced oxidation and light irradiation-assisted routes has been developed to prepare a ZnO rod-CdS/reduced graphene oxide (RGO) heterostructure. Here, graphene oxide nanosheets are reduced and loaded onto the surface of Zn spheres using a redox process. ZnO rods are generated from Zn spheres by a Pt-induced oxidation method, and CdS nanoparticles are then loaded onto the surface of RGO via a light irradiation-assisted method. The ZnO rod-CdS/RGO heterostructure exhibits 3.8 times higher photocatalytic hydrogen generation rate from an aqueous solution containing Na2S/Na2SO3 than the reference ZnO rod-CdS heterostructure under simulated solar light irradiation. The optimal contents of RGO nanosheets and CdS nanoparticles are 2 wt% and 20 at.%, respectively.