کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7854753 1508879 2014 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Pressure-assisted self-assembly technique for fabricating composite membranes consisting of highly ordered selective laminate layers of amphiphilic graphene oxide
ترجمه فارسی عنوان
تکنیک خودکارآمد با استفاده از فشار برای ساخت غشاء کامپوزیتی که شامل لایه های لاینهای انتخابی مرتبا از اکسید گرافن آمفیفیلیک
موضوعات مرتبط
مهندسی و علوم پایه مهندسی انرژی انرژی (عمومی)
چکیده انگلیسی
We prepare highly ordered flexible layers of graphene oxide (GO) on modified polyacrylonitrile substrates by the pressure-assisted self-assembly technique. This composite membrane shows excellent performance during the pervaporation separation of a 70 wt.% isopropyl alcohol (IPA)/water mixture: 99.5 wt% water in permeate and 2047 g m−2 h−1 permeation flux. Despite the specific GO deposition increase from 4.3 to 43.3 × 10−5 g cm−2 (ninefold layer thickness growth), its effect on the permeation flux is not significant, as manifested by only a little decrease in the flux. At 70 °C feed temperature, the permeate water concentration remains 99.5 wt% and the permeation flux reaches 4137 g m−2 h−1. The high selectivity may be due to the dense GO film consisting of highly ordered and packed laminates, allowing water but inhibiting IPA molecules to pass through. GO is demonstrated to be amphiphilic: water molecules adsorb first at the hydrophilic edge (hydroxides) and then rapidly diffuse through the hydrophobic core (mainly carbon), forming a water passage channel that promotes high permeation flux. When water molecules permeate through the GO layers, they accumulate and form a monolayer structure that pushes the successive layers away from each other, leading to widening of the d-spacing.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Carbon - Volume 68, March 2014, Pages 670-677
نویسندگان
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