کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7856926 | 1508890 | 2013 | 12 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Supercapacitors based on carbons with tuned porosity derived from paper pulp mill sludge biowaste
ترجمه فارسی عنوان
مخازن ابررسانایی بر اساس کربن با تخلخل تنظیم شده حاصل از زباله های لجن خام کاغذی کاغذ
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی انرژی
انرژی (عمومی)
چکیده انگلیسی
Hydrothermal carbonization followed by chemical activation is utilized to convert paper pulp mill sludge biowaste into high surface area (up to 2980 m2 gâ1) carbons. This synthesis process employs an otherwise unusable byproduct of paper manufacturing that is generated in thousands of tons per year. The textural properties of the carbons are tunable by the activation process, yielding controlled levels of micro and mesoporosity. The electrochemical results for the optimized carbon are very promising. An organic electrolyte yields a maximum capacitance of 166 F gâ1, and a Ragone curve with 30 W h kgâ1 at 57 W kgâ1 and 20 W h kgâ1 at 5450 W kgâ1. Two ionic liquid electrolytes result in maximum capacitances of 180-190 F gâ1 with up to 62% retention between 2 and 200 mV sâ1. The ionic liquids yielded energy density-power density combinations of 51 W h kgâ1 at 375 W kgâ1 and 26-31 W h kgâ1 at 6760-7000 W kgâ1. After 5000 plus charge-discharge cycles the capacitance retention is as high at 91%. The scan rate dependence of the surface area normalized capacitance highlights the rich interplay of the electrolyte ions with pores of various sizes.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Carbon - Volume 57, June 2013, Pages 317-328
Journal: Carbon - Volume 57, June 2013, Pages 317-328
نویسندگان
Huanlei Wang, Zhi Li, Jin Kwon Tak, Chris M.B. Holt, Xuehai Tan, Zhanwei Xu, Babak Shalchi Amirkhiz, Don Harfield, Anthony Anyia, Tyler Stephenson, David Mitlin,