کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7885939 | 1509785 | 2018 | 35 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Formation of BN from BCNO and the development of ordered BN structure: I. Synthesis of BCNO with various chemistries and degrees of crystallinity and reaction mechanism on BN formation
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Formation of BN from BCNO and the development of ordered BN structure: I. Synthesis of BCNO with various chemistries and degrees of crystallinity and reaction mechanism on BN formation Formation of BN from BCNO and the development of ordered BN structure: I. Synthesis of BCNO with various chemistries and degrees of crystallinity and reaction mechanism on BN formation](/preview/png/7885939.png)
چکیده انگلیسی
We synthesized BCNO compounds and investigated how the synthesis conditions impact i) BCNO formation, their chemistry and degree of crystallinity, and ii) BN formation from BCNO and its structural ordering. Heating boric acid (H3BO3) and melamine (C3H6N6) mixture yields intermediate amorphous BCNO compound. Increasing the synthesis temperature, and H3BO3 to C3H6N6 ratio promote BN formation and its structural ordering. We propose a possible reaction mechanism for BN formation from H3BO3 and C3H6N6 mixture and we explain the observations based on thermodynamic and kinetic considerations. An increase in synthesis temperature promotes BN formation since the reactions are endothermic. An increase in H3BO3 to C3H6N6 ratio promotes BN formation since theoretical BN formation temperature decreases with the above ratio. Furthermore, it enhances material transfer and mobility of the BN layer by forming B2O3 phase. We also propose a processing-structure correlation map that can help determining experimental conditions for single-phase amorphous BCNO synthesis.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ceramics International - Volume 44, Issue 13, September 2018, Pages 14980-14989
Journal: Ceramics International - Volume 44, Issue 13, September 2018, Pages 14980-14989
نویسندگان
Metin Ãrnek, Chawon Hwang, K. Madhav Reddy, Vladislav Domnich, Steven L. Miller, E. Koray AkdoÄan, Kevin J. Hemker, Richard A. Haber,