کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7886759 | 1509787 | 2018 | 14 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Electronic structure and magnetic properties of Ba1-xSrxCoFe11O19 hexaferrites
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
We have prepared Ba1-xSrxCoFe11O19 hexaferrite nanoparticles (NPs) by using a co-precipitation method. The crystal/electronic structures and magnetic properties were then studied. Results revealed that all Ba1-xSrxCoFe11O19 NPs with particle sizes of 100-300â¯nm crystallized in a hexagonal structure. Both the particle shape and the unit-cell parameters are changed when Sr content (x) increases. The analysis of the electronic structure based on the Fe and Co K-edge XAS spectra proved the oxidation states of Fe and Co to be 3â¯+â¯and 2â¯+â¯, respectively, which are stable versus an x change in Ba1-xSrxCoFe11O19. Local-structural studies also revealed the average bond length between Fe and O of 1.89-1.91â¯Ã
less changed by Sr doping. Though the electronic structures of Fe and Co were unchanged, the studies about the magnetic property demonstrated a strong dependence of Ms and Hc on Sr doping. While Ms decreases from 46.1â¯emu/g for xâ¯=â¯0-34.2â¯emu/g for xâ¯=â¯1, Hc tends to increase from 1630â¯Oe for xâ¯=â¯0 to ~ 2200â¯Oe for xâ¯=â¯0.5, but slightly decreases to 2040â¯Oe for xâ¯=â¯1. We think that the addition of the exchange interaction between Fe3+ and Co2+ ions and the changes of local-geometric structures and microstructures influenced directly Ms and Hc of NPs.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ceramics International - Volume 44, Issue 11, 1 August 2018, Pages 12132-12136
Journal: Ceramics International - Volume 44, Issue 11, 1 August 2018, Pages 12132-12136
نویسندگان
N. Tran, H.S. Kim, T.L. Phan, D.S. Yang, B.W. Lee,