کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7887801 | 1509792 | 2018 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synergistic effect of La and Co co-doping on room-temperature ferromagnetism enhancement of TiO2 nanoparticles
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The synergistic influence of lanthanum and cobalt co-doping on room temperature ferromagnetism (RTFM) of TiO2 system is investigated. A series of Ti0.97âxCo0.03LaxO2 nanoparticles were prepared and their structures and properties were systematically studied with X-ray diffraction (XRD), scanning electron microscopy (SEM), photoluminescence (PL) spectroscopy, UV-vis spectrophotometer, Raman spectra and magnetic measurement techniques, respectively. Detailed experimental characterizations indicate that the as-prepared La and Co co-doped samples exhibit single anatase phase, and all the samples exhibit strong visible photoluminescence associated with oxygen vacancies and a clear ferromagnetic hysteresis loop, both of which were dramatically enhanced with La and Co co-doping, and the maximum saturation magnetization (Ms) reaches 1.38Â emu/g at the La content of 6Â mol%. It is speculated that oxygen vacancies modulated by ionic La play an important role in the enhanced RTFM, which can be attributed to the bound magnetic polarons (BMPs) formed via ferromagnetic coupling between two neighboring Co2+ ions mediated by oxygen vacancy (F+ center). Our results present an alternative method to obtain high performance RTFM.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ceramics International - Volume 44, Issue 6, 15 April 2018, Pages 6362-6369
Journal: Ceramics International - Volume 44, Issue 6, 15 April 2018, Pages 6362-6369
نویسندگان
Hong Zhang, Xinhua Ouyang, Bo Yang, Ryan Lutes, Yonghao Ni,