کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7888137 | 1509793 | 2018 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Xanthate sensing properties of Pt-functionalized WO3 microspheres synthesized by one-pot hydrothermal method
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
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چکیده انگلیسی
WO3 microspheres in a hierarchical nanorod-assembled architecture were prepared by using a facile one-pot hydrothermal method. The morphology and structure of pure, and 1, 3, and 5 mol% Pt-functionalized WO3 microspheres were characterized by means of SEM, TEM, XRD, XPS and FTIR measurements. Structural characterizations demonstrated that these WO3 microspheres assembled by numerous one-dimensional WO3 nanorods were approximately 2-5 µm in diameter. The nanorods with their diameters in the range of 70-90 nm showed a single crystal hexagonal structure. Gas sensors based on pure and Pt-functionalized WO3 microspheres showed reversible response and outstanding selectivity to xanthate gas at the operating temperature range of 75-175 °C. The sensor response increased with the increase of xanthate gas concentration. The highest response of 102.7 was obtained for the sensor based on 3 mol% Pt-functionalized WO3 microspheres to 100 ppm xanthate gas at an operating temperature of 100 °C, which could be ascribed to the large effective surface area and high porosity of WO3 microspheres as well as the catalytic effect of Pt nanoparticles.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ceramics International - Volume 44, Issue 5, 1 April 2018, Pages 4814-4823
Journal: Ceramics International - Volume 44, Issue 5, 1 April 2018, Pages 4814-4823
نویسندگان
Tingting Li, Yanbai Shen, Sikai Zhao, Xiangxiang Chen, Guodong Li, Rui Lu, Lijia Zhu, Hansen Li, Dezhou Wei, Yansong Shen,