کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7901055 | 1510431 | 2015 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Thermal properties, density and structure of percalcic and peraluminus CaO-Al2O3-SiO2 glasses
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Calcium silicate and aluminosilicate glasses with various SiO2 contents (10-76 mol%) were prepared in the wide range of [Al2O3]/[CaO] molar ratio from 0.10 to 4.00 by conventional melt-quenching method and an aerodynamic levitation device for a part of peraluminus glasses. Variations of glass transition temperature, the coefficient of linear expansion, and ionic packing factor derived from density measurements with [Al2O3]/[CaO] molar ratio were studied. The glass structures of SiO4 three dimensional network, mixed anions of (Si, Al)O4 tetrahedra, isolated AlO4 and Al-O-Al linkages were evaluated by FT-IR measurements. Compositional dependences of the properties are qualitatively related to the glass structure examined by IR spectroscopy and the proportions of AlOx (x = 4, 5, 6) species evaluated in a previous study by using 27Al MQ NMR spectroscopy.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Non-Crystalline Solids - Volume 411, 1 March 2015, Pages 5-12
Journal: Journal of Non-Crystalline Solids - Volume 411, 1 March 2015, Pages 5-12
نویسندگان
Shoji Takahashi, Daniel R. Neuville, Hiromichi Takebe,