کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7935230 | 1513051 | 2018 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Neutral organic redox pairs based on sterically hindered hydroquinone/benzoquinone derivatives for dye-sensitized solar cells
ترجمه فارسی عنوان
جفت ارگانیک آلی با استفاده از مشتقات هیدروکینون / بنزوئیونون مضر است که برای سلول های خورشیدی حساس شده به رنگ
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کلمات کلیدی
سلول های خورشیدی حساس شده به رنگ، الکترولیت مایع جفت بازو آلی، هیدروکینون، بنزووینون،
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی انرژی
انرژی های تجدید پذیر، توسعه پایدار و محیط زیست
چکیده انگلیسی
Substituted derivatives of hydroquinone/benzoquinone were studied as organic redox mediators in the electrolyte for dye-sensitized solar cells (DSSCs). Thus, di-tert-butylhydroquinone (DTHQ), thymohydroquinone (ThymHQ) and phenylhydroquinone (PhHQ), were combined with their oxidized counterparts to form the pairs DTHQ/DTBQ, ThymHQ/ThymBQ, and PhHQ/PhBQ. In general, the characteristic parameters of the DSSCs with the substituted derivatives surpassed those of the DSSC with the unsubstituted hydroquinone/benzoquinone electrolyte. The short-circuit current (JSC) of the devices using DTHQ/DTBQ and ThymHQ/ThymBQ (13.61â¯mAâ¯cmâ2 and 12.56â¯mAâ¯cmâ2, respectively) are comparable to the JSC obtained for cobalt(II/III) tris(bipyridine) as a reference electrolyte (14.54â¯mAâ¯cmâ2). However, parameters such as open-circuit voltage (VOC) and fill factor (FF) (547â¯mV and 0.48, respectively) are far from competitive. The best photovoltaic performance was obtained for the pair ThymHQ/ThymBQ using a triphenylamine (TPA)-based organic dye (LEG4) as sensitizer and a hybrid counter electrode with poly(3,4-ethylenedioxythiophene) (PEDOT) and graphene. These experimental conditions give under 1 sun (98%) the highest efficiency (ηâ¯=â¯3.19%); low-light intensities of 12.3% and 51.8% suns lead to efficiencies of 3.34% and 3.29%, respectively. Electrochemical impedance spectroscopy (EIS) revealed that the main cause for loss in photocurrent is the low recombination resistance compared to Co(II/III) as reference electrolyte. Based on the EIS analysis, a down-shift of the conduction band of TiO2 was found for all assembled devices containing the organic redox mediators, which explains the low VOC values for these derivatives.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solar Energy - Volume 167, June 2018, Pages 76-83
Journal: Solar Energy - Volume 167, June 2018, Pages 76-83
نویسندگان
Natalie Flores-DÃaz, Andrea Soto-Navarro, Marina Freitag, Guy Lamoureux, Leslie W. Pineda,