Initial experimental evaluation of crud-resistant materials for light water reactors

The buildup of fouling deposits on nuclear fuel rods, known as crud, continues to challenge the worldwide fleet of light water reactors (LWRs). Crud causes serious operational problems for LWRs, including axial power shifts, accelerated fuel clad corrosion, increased primary circuit radiation dose rates, and in some instances has led directly to fuel failure. Numerous studies continue to attempt to model and predict the effects of crud, but each assumes that it will always be present. In this study, we report on the development of crud-resistant materials as fuel cladding coatings, to reduce or eliminate these problems altogether. Integrated loop testing experiments at flowing LWR conditions show significantly reduced crud adhesion and surface crud coverage, respectively, for TiC and ZrN coatings compared to ZrO2. The loop testing results roughly agree with the London dispersion component of van der Waals force predictions, suggesting that they contribute most significantly to the adhesion of crud to fuel cladding in out-of-pile conditions. These results motivate a new look at ways of reducing crud, thus avoiding many expensive LWR operational issues.