کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7989994 | 1516125 | 2018 | 46 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Lithium phosphorous oxynitride (LiPON) coated NiFe2O4 anode material with enhanced electrochemical performance for lithium ion batteries
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Polycrystalline nickel ferrite (NiFe2O4) thin films were fabricated by pulsed laser deposition (PLD) and coated with nanometer layer of lithium phosphorus oxynitride (LiPON) by radio frequency magnetron sputtering (RF sputtering). Physical characterizations demonstrated that NiFe2O4 thin films were not destroyed by LiPON coating with 50â¯nm thickness. Discharge capacity of LiPON coated NiFe2O4 thin film after 50 cycles at 5â¯Î¼Aâ¯cmâ2 was 849â¯mAh gâ1, much higher than the counterpart value of pristine NiFe2O4 thin film (449â¯mAh gâ1), while rate capability was also greatly enhanced. Ex situ TEM investigation confirmed the two-steps reaction mechanism between NiFe2O4 and Li, which includes an irreversible decomposition reaction of NiFe2O4 in the first discharge process and reversible reactions between NiO, Fe2O3 and their nanosized metal particles afterward. The significant improvement on the electrochemical performance was ascribed to the amorphous LiPON layer on the surface, which suppressed the volume expansion of electrode, the formation of delaminated particles and generation of cracks on electrode surface, as proved by ex situ SEM and AFM results. The LiPON coating is an effective approach to enhance the electrochemical performance of conversion materials for lithium ion batteries.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 769, 15 November 2018, Pages 110-119
Journal: Journal of Alloys and Compounds - Volume 769, 15 November 2018, Pages 110-119
نویسندگان
Kaiyuan Wei, Yu Zhao, Yixiu Cui, Jiali Wang, Yanhua Cui, Rongtao Zhu, Quanchao Zhuang, Mingzhe Xue,