کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7990550 | 1516129 | 2018 | 22 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Studying of doping boron and carbon in LaFe11.6Si1.4 magnetocaloric alloy by experimental and density-functional methods
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Both magnetic transition and magnetocaloric properties of LaFe11.6Si1.4 doped with boron (B) and carbon (C) were investigated. Experimental data showed that nearly pure Ï1 phase was obtained in LaFe11.6Si1.4, LaFe11.6Si1.4B0.06 and LaFe11.6Si1.4C0.06 alloys after annealing at 1373â¯K for 100â¯h. All annealed samples underwent a first-order magnetic transition. B doping decreased the magnetic transition temperature from 192â¯K to 188â¯K, whereas C doping increased to 206â¯K. In combination with X-ray diffraction results, the density-functional theory was used to reconstruct the unit-cell in order to understand the magnetic transition behavior. The results suggested that almost all B atoms occupy 96i FeII/Si substitutional site, and all C atoms prefer 24d interstitial site in the present given conditions. The annealed samples possessed the maximum magnetic entropy changes higher than 20â¯J/(kgâ
K) under a magnetic field change of 3â¯T, and their effective refrigeration capacities reached 200â¯J/kg.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 765, 15 October 2018, Pages 538-543
Journal: Journal of Alloys and Compounds - Volume 765, 15 October 2018, Pages 538-543
نویسندگان
Yuting Dai, Yuqiang Li, Zhishuai Xu, Zhiping Luo, Ke Han, Qijie Zhai, Hongxing Zheng,