کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7991072 | 1516132 | 2018 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Enhanced reversible hydrogen desorption properties and mechanism of Mg(BH4)2-AlH3-LiH composite
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Enhanced reversible hydrogen desorption properties and mechanism of Mg(BH4)2-AlH3-LiH composite Enhanced reversible hydrogen desorption properties and mechanism of Mg(BH4)2-AlH3-LiH composite](/preview/png/7991072.png)
چکیده انگلیسی
The Mg(BH4)2-AlH3-xLiH (xâ¯=â¯0, 0.5, 1) novel ternary composites have been synthesized through mechanical ball milling, their favorable dehydrogenation properties and mechanism have been experimentally investigated. It can be found that during ball milling, a slight amount of Mg(BH4)2 would react with LiH and transform into LiBH4, while most Mg(BH4)2 remained stable after ball milling. Two major dehydrogenation steps can be detected in the Mg(BH4)2-AlH3-xLiH composite, which belong to the decomposition of AlH3 and Mg(BH4)2, respectively. Remarkably, the onset hydrogen desorption temperature of Mg(BH4)2-AlH3-xLiH composite can be reduced to 125.9â¯Â°C, with a total hydrogen desorption capacity of 10.3â¯wt%. It is worth emphasizing that the reversible dehydrogenation capacity is obviously improved to 3.8â¯wt%, compared to the Mg(BH4)2-AlH3 composite. This reversible capacity can be held for 3 cycles without obvious degeneration. Microstructural analysis on de/rehydrogenated composite has identified the regeneration of [BH4]- in Mg(BH4)2-AlH3-0.5LiH composite and revealed the role of LiH in the cycling hydrogen desorption and absorption processes. The formation of LiBH4 and MgH2 resulted from the rehydrogenation between MgAlB4 and LiH could be helpful for the stability of reversible hydrogen storage performance.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 762, 25 September 2018, Pages 548-554
Journal: Journal of Alloys and Compounds - Volume 762, 25 September 2018, Pages 548-554
نویسندگان
Jiaguang Zheng, Xuezhang Xiao, Yan He, Man Chen, Meijia Liu, Shouquan Li, Lixin Chen,